Introduction of Metallurgy
Metallurgy is the science and technology of metals. The worker of metals is mentioned in the Bible, Greek and Norse mythology. It is an art that has been practiced since ancient times. The ancient men knew and used many native metals.
Gold
was used for ornaments, plates and utensils as early as 3500 B.C. The art of
smelting, refining and shaping metals was highly developed by both the
Egyptians and the Chinese. The ancient Egyptians knew how to separate iron from
its ore and that steelhead the ability to harden. But iron was not used widely
before 1000 B.C. Iron was not popular with ancient people because of its
tendency to rust and they preferred working with gold, silver, copper, brass
and bronze.
Knowledge
of dealing with metals was generally passed directly from master to apprentice
in the Middle Ages, leading to an aura of superstition surrounding many of the
processes. Very little was written on the metallurgical processes until
Biringuccio published his “Pirotechnia” in 1540 followed by Agricola’s “De Re
Metallurgica” in 1556. In succeeding years, much knowledge was added to the
field by people trying to duplicate the composition and etched structure of
Damascus steel.
Until
the beginning of the last quarter of the nineteenth century, most of the investigations
of metal structure had been macroscopic (by eye) and superficial. The science
of the structure of metals was almost nonexistent. The situation was ripe for
the detailed attention of individuals whose background was more scientific than
practical. The individual was responsible for the period of rapid development
that followed was Henry Clifton Sorby.
Sorby
was an amateur English scientist who started with a study of meteorites and
then went on to study metals. In September 1864, Sorby presented a paper to the
British Association for the Advancement of Science in which he exhibited and
described a number of microscopical photographs of various kinds of iron and
steel. This paper marks the beginning of the metallography, the field concerned
with the use of the microscope to study the structure of metals. It seems that
while many people appreciated the value of Sorby’s studies at the time they
were done, none of them had sufficient interest to develop the technique independently
and metallography lay dormant for almost twenty years.
Additional
work by Martens in Germany (1878) revived Sorby’s interest in metallurgical
problems and in 1887 he presented a paper to the Iron and Steel Institute which
summarized all his work in the field. Considerable attention was now generated
by both scientists and industrial metallurgists in other countries. In the
early part of the twentieth century, Albert Sauveur convinced American steel
companies that the microscope was a practical tool to aid in the manufacture and
heat treatment of steel.
About
1922, more knowledge of the structure and properties of metals was added by the
application of x-ray diffraction and wave mechanics.
Metallurgy
is really not an independent science since many of its fundamental concepts are
derived from physics, chemistry and crystallography.
The
metallurgist has become increasingly important in modern technology. Years ago,
the great majority of steel parts were made of cheap, low-carbon steel that
will machine and fabricate easily. Heat treatment was reserved largely for
tools. Designers were unable to account for structural inhomogeneity, surface
defects etc. It was considered good practice to use large factors of safety.
Consequently, machines were much heavier than they should have been and the
weight was considered a mark of quality. This attitude has persisted to some
extent, to the present time but has been discouraged under the leadership of
the aircraft and automotive industries. They have emphasized the importance of
the strength-weight ratio in good design and this has led to the development of
new high-strength, lightweight alloys.
New
technical applications and operating requirements pushed to higher levels have
created a continued need for the development of new alloys. For example, an exciting
development has been the Wankel rotary engine. It is an internal combustion engine
of unusual design that is more compact, lighter and mechanically far simpler
than the ordinary reciprocating piston motor of equivalent horsepower. A
particularly bothersome problem has been the seals between the rotor and the
metal wall. Originally, the seals were made of carbon and seldom lasted more
than 20,000 miles. Research developed a new sintered titanium-carbide alloy
seal which has given life-times of up to 100,000 miles.
The
metallurgical field may be divided in two large groups. They are:
1. Process or Extractive metallurgy- The science of
obtaining metals from their ores, including mining, concentration, extraction
and refining metals and alloys.
2. Physical metallurgy- The science concerned with the
physical and mechanical characteristics of metals and alloys. This field
studies the properties of metals and alloys as affected by three variables.
a.
Chemical
composition- The chemical constituents of the alloy.
b.
Mechanical
treatment- Any operation that causes a change in shape such as rolling,
drawing, stamping, forming or machining.
c.
Thermal or Heat
treatment- The effect of temperature and rate of heating and cooling.
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